Energy levels of the weakly interacting radicals |
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Authors: | Marek Naroznik Jan Niedzielski |
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Affiliation: | (1) Center of Scientific Research and Didactics, Agricultural and Teachers' University, 08-110 Siedlce, Poland;(2) Chemistry Department, Warsaw University, PI-02-089 Warsaw, Poland |
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Abstract: | Energy levels of the weakly interacting radicals are estimated on the basis of planar methyl radical interaction as a model. These levels depend on the given separation r between the centers of mass. The appropriate Schrödinger equation is solved by using the Brillouin-Wigner series method. Analytical forms for the integrals used to estimate matrix elements are derived. The principle of total momentum conservation is strictly obeyed. Some energy levels cannot be estimated as a result of divergence. |
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Keywords: | Methyl radical recombination Energy levels |
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