Novel tetramethoxy resorcinarene bis-crown ethers |
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Authors: | Salorinne Kirsi Nissinen Maija |
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Institution: | Nanoscience Center, Department of Chemistry, University of Jyv?skyl?, P.O. Box 35, FIN-40014 JYU, Finland. |
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Abstract: | The synthesis and characterization of new tetramethoxy resorcinarene bis-crown ethers BC4 and BC5 are described. The complexation properties of the compounds toward alkali metal cations were studied by 1H NMR spectroscopy and X-ray crystallography, which revealed that BC5 can accommodate two cations simultaneously inside the crown pockets formed by the crown ether bridges and the resorcinarene skeleton. reaction: see text]. |
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