Oxidation of aliphatic alcohols with the lead tetraacetate—metal halide system under mechanical activation |
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| Authors: | N. I. Kapustina V. D. Makhaev A. P. Borisov G. I. Nikishin |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Rissian Federation;(2) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | The mechanochemical oxidation ofn-pentanol,n-hexanol, andn-octanol with the Pb(OAc)4-MHal system (M=Li, K; Hal=Cl, Br) in the absence of a solvent affords esters. and secondary alcohols with the composition C8H17OH and C9H19OH give ketones. Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1870–1873, November, 2000. |
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| Keywords: | mechanical activation oxidation aliphatic alcohols lead tetraacetate metal halide esters ketones |
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