| CO2选择氧化低碳烷烃的研究进展 |
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| 引用本文： | 张法智,徐柏庆. CO2选择氧化低碳烷烃的研究进展[J]. 化学进展, 2002, 14(1): 56 |
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| 作者姓名： | 张法智 徐柏庆 |
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| 作者单位： | 清华大学化学系一碳化学与化工国家重点实验室 北京 100084 |
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| 摘 要： | 本文以低碳烷烃的选择催化氧化反应为对象，对几种CO2选择氧化低碳烷烃的反应工艺进行了归纳总结，重点分析讨论了催化氧化反应中CO2作为氧化剂的作用机制，并提出了研究展望。
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| 关 键 词： | 温室气体 二氧化碳 低碳烷烃 合成气 氧化脱氢 芳构化 选择氧化 |
| 收稿时间： | 2000-12-01 |
| 修稿时间： | 2001-05-01 |
Recent Development in the Selective Oxidation of Light Alkanes by Oxidant CO2 |
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| Zhang Fazhi,Xu Boqing. Recent Development in the Selective Oxidation of Light Alkanes by Oxidant CO2[J]. Progress in Chemistry, 2002, 14(1): 56 |
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| Authors: | Zhang Fazhi Xu Boqing |
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| Affiliation: | State Key Lab of C1 Chemistry and Technology, Department of Chemistry, Tsinghua University, Beijing 100084, China |
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| Abstract: | Recent advances in the selective oxidation of alkanes by using CO2 as the oxidant were reviewed. The subjects included in this articles are the CO2 reforming of methane to syngas, the oxidative coupling of methane to ethylene and ethane byCO2 oxidative dehydrogenation and aromatization of light alkanes by CO2. Discussion is focused on the role of CO2 in the selective oxidative reactions and the related mechanisms. |
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| Keywords: | greenhouse gases CO2 light alkanes syngas oxidative dehydrogenation aromatization selective oxidations |
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