1,1-Carboboration route to substituted naphthalenes |
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Authors: | Liedtke René Harhausen Marcel Fröhlich Roland Kehr Gerald Erker Gerhard |
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Affiliation: | Organisch-Chemisches Institut, Westf?lische Wilhelms-Universit?t, Corrensstrasse 40, 48149 Münster, Germany. |
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Abstract: | 1,2-Bis(alkynyl)benzene derivatives react with strongly electrophilic boranes to yield in boryl-functionalized bulky naphthalene derivatives by means of a sequence of 1,1-carboboration reactions. These substrates can be functionalized by transition metal catalyzed cross-coupling reactions. |
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