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1,1-Carboboration route to substituted naphthalenes
Authors:Liedtke René  Harhausen Marcel  Fröhlich Roland  Kehr Gerald  Erker Gerhard
Affiliation:Organisch-Chemisches Institut, Westf?lische Wilhelms-Universit?t, Corrensstrasse 40, 48149 Münster, Germany.
Abstract:1,2-Bis(alkynyl)benzene derivatives react with strongly electrophilic boranes to yield in boryl-functionalized bulky naphthalene derivatives by means of a sequence of 1,1-carboboration reactions. These substrates can be functionalized by transition metal catalyzed cross-coupling reactions.
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