Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds |
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| Authors: | Lindqvist Markus Sarnela Nina Sumerin Victor Chernichenko Konstantin Leskelä Markku Repo Timo |
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| Affiliation: | Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, P. O. Box 55, FIN-00014, Finland. |
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| Abstract: | Aromatic carbonyl compounds in combination with B(C(6)F(5))(3) are able to activate H(2) heterolytically. The reactivity of the carbonyl-B(C(6)F(5))(3) adduct is initiated by its thermal dissociation into components. After H(2) addition, aromatic carbonyl compounds convert into aryl-substituted methanes or alcohols. |
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