Predictions of multiphoton resonances in SF6 and SiF4 |
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Authors: | Chris W Patterson AS Pine |
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Institution: | University of California, Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA;Molecular Spectroscopy Division, NBS, Washington, DC 20234, USA |
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Abstract: | The frequency dependence of the multiphoton resonances to the rotation-vibrational levels of the first two ν3 overtones are calculated for SF6 and SiF4. From these calculations we can identify most of the features seen in the high intensity SF6 absorption data and predict those features that would be seen in similar SiF4 data. |
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