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Enhanced desulfurizing flotation of coal using sonoelectrochemical method
Authors:Hong-Xi Zhang  Xiao-Yang Hou  Shi-Xun Xu  Zhi-Long Li  Hai-Feng Yu  Xue-Hua Shen
Institution:1. College of Life Science, Tarim University, Alaer 843300, Xinjiang, China;2. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Abstract:Enhanced desulfurizing flotation of low sulfur coal was investigated using sonoelectrochemical method. The supporting electrolyte used in this process was sodium chloride and the additive was anhydrous ethanol. The effects of treatment conditions on desulfurization were studied by a single-factor method. The conditions include anhydrous ethanol concentration, sodium chloride concentration, sonoelectrolytic voltage, sonoelectrolytic temperature, sonoelectrolytic time and coal sample granulometry. The optimal experimental conditions achieved for anhydrous ethanol concentration, sodium chloride concentration, sonoelectrolytic voltage, sonoelectrolytic temperature and sonoelectrolytic time are 1.7 mol L?1, 5.1 × 10?3 mol L?1, 10 V, 70 °C, 50 min achieved for a ?0.18 mm coal sample. Optimal conditions cause a sulfur reduction of up to 69.4%. The raw and treated coals were analyzed by infrared spectroscopy and a chemical method. Pyritic sulfur, organic sulfur, ash as well as moisture are partially removed. The combination of high sulfur reduction, high yield, as well as high ash reduction was obtained in the newly developed method of enhanced flotation by sonoelectrochemistry. Ultrasound irradiation promotes electron transfer efficiency and increases clean coal yield.
Keywords:Sonoelectrochemistry  Enhanced flotation  Oxidation  Desulfurization  Sonocavitation
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