| 一类新型二胺的合成研究 |
| |
| 引用本文： | 吴鸣虎,许韵华.一类新型二胺的合成研究[J].咸宁学院学报,1994(4). |
| |
| 作者姓名： | 吴鸣虎 许韵华 |
| |
| 作者单位： | 咸宁师专，山西职工医学院 |
| |
| 摘 要： | 本文报道以两种不同的还原体系ＮＨ２ＮＨ２—ＲａｎｅｙＮｉ／Ｃ２Ｈ５ＯＨ和Ａｌ—Ｈｇ／Ｈ２Ｏ，将３—取代—１，５—二（２—硝基苯氧基）—３—氨杂戊烷（Ⅰ—Ⅶ）还原为相应的二胺（Ⅷ—ⅹⅨ）．取代基分别为—ＣＨ２—ＣＨ＝ＣＨ２，—Ｃ４Ｈ９—ｎ，—ＣＨ２ＣＨ２ＯＣＨ３，—ＣＨ２ＣＨ２ＯＣ２Ｈ５，—ＣＨ２ＣＨ２ＯＣ４Ｈ９—ｎ，—ＣＨ２ＣＨ２ＯＣＨ２ＣＨ２ＯＣＨ３，—ＣＨ２ＣＨ２ＯＣＨ２ＣＨ２ＯＣ４Ｈ９—ｎ．产物经元素分析、１ＨＮＭＲ和ＭＳ证实其结构．
|
| 关 键 词： | 二硝基化合物 二胺 还原 合成 |
Studies on the synthesis of a novel type diamines |
| |
| Wu Minghu, Xu Yunhua.Studies on the synthesis of a novel type diamines[J].Journal of Xianning College,1994(4). |
| |
| Authors: | Wu Minghu Xu Yunhua |
| |
| Institution: | Wu Minghu; Xu Yunhua (Xianning Teachers College) (Shanxi Professional's Medical College) |
| |
| Abstract: | This Paper reports the teduction of 3--subotituted --1, 5--dis (2--nitrophenoxy) 3--azapentane into the corresponding diamine by two different systems (NH2NH2 -- Raney Ni/C2H5OH,A1--Hg/H2O). The substituents are -- CH2-- CH= CH2, -- C4H9 -- n, -- CH2CH2OCH3, -CH2CH2OC2H5, --CH2CH2OC4H9 -- n, CH2CH2OCH2CH2OCH3 and CH2 CH2 OCH2CH2OC4H9 -- n, respectively. All these compounds wete idenaned with elemental analysis,1HNMR and MS. |
| |
| Keywords: | dinitro compound diamines reduction synthesis |
| 本文献已被 CNKI 等数据库收录！ |
|
