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大孔吸附树脂对邻甲酚的吸附行为研究
引用本文:李洁莹,陈金龙,费正皓,陆朝阳,李爱民,刘福强,张全兴. 大孔吸附树脂对邻甲酚的吸附行为研究[J]. 离子交换与吸附, 2004, 20(5): 430-437
作者姓名:李洁莹  陈金龙  费正皓  陆朝阳  李爱民  刘福强  张全兴
作者单位:污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093;污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093;污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093;污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093;污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093;污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093;污染控制与资源化国家重点实验室,南京大学环境工程系,南京,210093
基金项目:国家自然科学基金资助项目 (20274017)
摘    要:研究了大孔吸附树脂NDA—909吸附水溶液中邻甲酚的热力学特征,并与Amberlite XAD—4树脂进行了比较.通过吸附动力学实验,初步探讨了初始温度对吸附过程的影响。结果表明,NDA—909对邻甲酚的吸附符合Freundlich经验公式,表现为放热的物理吸附过程.此外吸附速率受颗粒内扩散和其它类型扩散的共同控制。

关 键 词:邻甲酚  大孔吸附树脂  吸附热力学  吸附动力学
文章编号:1001-5493(2004)05-0430-08
修稿时间:2003-12-03

ADSORPTION OF O-CRESOL ON MACROPOROUS ADSORBENTS
LI Jieying CHEN Jinlong FEI Zhenghao LU Zhaoyang LI Aimin LIU Fuqiang ZHANG Quanxing State Key Laboratory of Pollution Control and Resources Reuse. ADSORPTION OF O-CRESOL ON MACROPOROUS ADSORBENTS[J]. Ion Exchange and Adsorption, 2004, 20(5): 430-437
Authors:LI Jieying CHEN Jinlong FEI Zhenghao LU Zhaoyang LI Aimin LIU Fuqiang ZHANG Quanxing State Key Laboratory of Pollution Control and Resources Reuse
Affiliation:LI Jieying CHEN Jinlong FEI Zhenghao LU Zhaoyang LI Aimin LIU Fuqiang ZHANG Quanxing State Key Laboratory of Pollution Control and Resources Reuse,Department of Environmental Engineering,Nanjing University,Nanjing 210093,China
Abstract:A comparison study was made on the adsorption behaviors of o-cresol onto the macroporous adsorbent NDA-909 with that on the Amberlite XAD-4, including the static equilibrium adsorption, the adsorption thermodynamics properties and so on. In addition, study on adsorption kinetics of o-cresol on NDA-909 was also carried out through static experiments. The effect of initial temperature on o-cresol sorption was evaluated. The results showed that the adsorption date fit well into the Freundlich isotherm, and the uptake of o-cresol on NDA-909 was a type of physical adsorption. Besides, the rate of adsorption was under the control of intra-particle diffusion and external diffusion simultaneously.
Keywords:O-cresol  Macroporous adsorbent  Adsorption kinetics  Adsorption thermodynamics.  
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