Rhenium-catalyzed deoxygenation of epoxides without adding any reducing agent |
| |
| Authors: | Sara CA SousaAna C Fernandes |
| |
| Institution: | Centro de Química Estrutural, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal |
| |
| Abstract: | This work reports a novel method for the deoxygenation of epoxides catalyzed by oxo-rhenium (V) and (VII) complexes without adding any reducing agent. This eco-friendly methodology was successfully applied to the deoxygenation of several epoxides with tolerance of different functional groups and high reusability of the catalysts ReIO2(PPh3)2 and ReOCl3(PPh3)2. |
| |
| Keywords: | Epoxides Deoxygenation Oxo-rhenium complexes Alkenes Eco-friendly methodology |
| 本文献已被 ScienceDirect 等数据库收录！ |
