Thermal Decomposition of Thallium(I) Bis-oxalatodiaquaindate(III) Monohydrate |
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| Authors: | Kebede T Ramana K V Rao M S P |
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| Institution: | (1) Bio-inorganic Chemistry Laboratories, School of Chemistry, Andhra University, Visakhapatnam, India |
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| Abstract: | Thallium(I) bis-oxalatodiaquaindate(III) monohydrate was obtained by precipitation of indium(III) withoxalic acid from slightly
acidic solution in the presence of thallium(I). The complex was subjected to chemical analysis. The thermal decomposition
behavior of the complex was studied using TG, DTA and DTG techniques. The solid complex salt and the intermediate product
of its thermal decomposition were characterized using IR absorption and X-ray diffraction spectra. Based on data from these
physicochemical investigations the structural formula of the complex was proposed as TlIn (C2O4)2 (H2O)2]⋅H2O.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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| Keywords: | bis-oxalates indium(III) IR data thallium(I) salt thermal analysis X-ray diffraction |
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