On the Compensation Effect at the Form of the Differential Conversion Function |
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| Authors: | P Budrugeac E Segal |
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| Institution: | (1) EUROTEST S. A., Spaiul Unirii, Nr. 313, Bucharest, 73204, P.O. Box 77-4, Romania;(2) Department of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bd. Republicii, Nr. 13, Bucharest, Romania |
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| Abstract: | From the general form of the rate equation under non-isothermal conditions, some relationships showing the existence of a
compensation effect due to the change of the analytical form of the differential conversion function were derived. These relationships
were checked for some simulated TG curves, as well as thermogravimetric data corresponding to the degradation of some polymers
and to the decomposition of calcium carbonate.
This revised version was published online in July 2006 with corrections to the Cover Date. |
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| Keywords: | compensation effect non-isothermal kinetic parameters |
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