Palladium-catalyzed cross-coupling of H-phosphinate esters with chloroarenes |
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Authors: | Deal Eric L Petit Christelle Montchamp Jean-Luc |
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Institution: | Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA. |
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Abstract: | The palladium-catalyzed cross-coupling reaction between H-phosphinate esters and chloroarenes or chloroheteroarenes is described. This reaction is the first general metal-catalyzed phosphorus-carbon bond-forming reaction between a phosphorus nucleophile and chloroarenes. |
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