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| Synthesis and Properties of Three Tris(1,10-phenanthroline) ruthenium (Ⅱ) Derivatives | |
| 作者姓名： | Fa Ming TIAN Peng WANG Guo Yi ZHU (Laboratory of Electroanalytical Chemistry National Analytical Research Center ofElectrochemistry and Spectroscopy Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022) |
| 作者单位： | Laboratory of Electroanalytical Chemistry，National Analytical Research Center ofElectrochemistry and Spectroscopy，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022 |
| 摘 要： | MThekeymaterials,5-amino-l,10-phenanthrolineandetS-Ru(phew,CI,,werepreparedbythemethodsofreferences"'.Synthesisofla,foandicEquimolaramountsofcorrespondingto-bromo-alkyIacyIohIondewasaddeddropwisetoasuspensionof5-amino-l,10-phenanthrolineandsodiumdicarbonateindryacetonitrilewithstirringatroomtemperatureundernitrogenfor4-6hours.Thentheresultingsolidwasfilteredandwashedbyacetonitrile,5%sodiumbicarbonateaqueoussolutionandwaterinturn.Afterbeingdriedicvacuo,yellowmicrocrystalsla-cwereobtained.Sy… |
| 关 键 词： | Tris(1.10-phenanthroline)ruthemium(Ⅱ) complexes synthesis electrochemistry fluorescence |
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