ESR study of ordered Ti(III) clusters in frozen solutions |
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| Authors: | A. A. Altynnikov O. V. Kalinkina V. F. Anufrienko A. A. Shubin S. V. Vossel V. V. Zakharov N. N. Bulgakov |
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| Affiliation: | (1) Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia |
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| Abstract: | The ESR spectrum of exchange-coupled Ti3+ ions of g   ge has been observed in dissolution products of metallic titanium in HCl, evidencing the formation of chloride clusters of mutually ordered Ti3+ ions in dz2-ground state in distorted tetrahedral coordination. The cooperative Jahn-Teller effect (CJTE) defines orbital ordering of the d1 of Ti3+ ions in the cluster. |
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