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Investigations on the determination of NO2 with galvanic nitrate solid electrolyte cells
Authors:V. Brü  ser, S. Jakobs, H. -H. Mö  bius  U. Schö  nauer
Affiliation:(1) Institut für Physikalische Chemie, Universität Greifswald, Soldtmannstrasse 23, D-17489 Greifswald, Germany;(2) Roth-Technik GmbH, Forschung für Automobil- und Umwelttechnik, Max-Roth-Strasse, D-76571 Gaggenau, Germany
Abstract:Solid electrolyte cells for detecting NO2 with Ba(NO3)2 or Sr(NO3)2 partially replaced by gamma-Al2O3 as solid electrolytes have been studied. The cell tension depends on the NO2- as well as on the NO-concentration. Investigations of the establishment of the NO2-NO-O2-equilibrium by the catalytic effects of the used electrode materials Pt and Au have shown that a decomposition of NO2 below 400°C cannot be expected.17th Communication on oxoanionic solid electrolytes and their possible applications; 16th Communication see Solid State Ionics 51:183–185 (1992)Extension of a part of the lecture of V. Brüser, S. Jakobs, H.-H. Möbius and U. Schönauer ldquoGalvanische NO2-Sensoren mit Nitrat-Festelektrolytenrdquo given in Feldberg, 3. 6. 1993
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