| 新型水溶性金属卟啉配合物的合成及其光敏性质 |
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| 引用本文： | 曹锡章,王杏乔,张密林,杨国煜. 新型水溶性金属卟啉配合物的合成及其光敏性质[J]. 无机化学学报, 1992, 8(1): 12-16 |
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| 作者姓名： | 曹锡章 王杏乔 张密林 杨国煜 |
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| 作者单位： | 吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系 长春 130023，长春 130023，长春 130023，长春 130023 |
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| 摘 要： | 本文采用一种新方法合成了三种水溶性极好的新型金属卟啉配合物—5、10、15、20四(对-N-丙磺酸负离子,-N,N-二甲苯胺基)卟啉锌、铜、钴(Zn(Ⅱ)、Cu(Ⅱ)、Co(Ⅱ)TDMAPTPS)和一种新的卟啉,5、10、15、20四(对-N,N-二甲基-N-磺酸负离子苯胺基)双-N-丙磺酸卟啉(TDMAPSPS)。通过红外、紫外、核磁和元素分析等手段对它们进行了表征、确定了它们的结构。采用荧光分析和甲基紫精还原反应研究了它们的光敏性,结果表明,光敏性的强度有如下规律: Zn(Ⅱ)TDMAPTPS>TDMAPSPS>Cu(Ⅱ)TDMAPTPS>Co(Ⅱ)TDMAPTPS。
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| 关 键 词： | 金属卟啉 合成 光敏性 锌 铜 钴 |
| 收稿时间： | 1989-07-31 |
SYNTHESIS OF THE NEW WATER-SOLUBLE METALLOPORPHYRIN COMPLEXES AND THEIR PROPERTIES OF LINGT-SENSITIVITY |
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| Cao Xizhang,Wang Xingqiao,Zhang Milin and Yang Guoyu. SYNTHESIS OF THE NEW WATER-SOLUBLE METALLOPORPHYRIN COMPLEXES AND THEIR PROPERTIES OF LINGT-SENSITIVITY[J]. Chinese Journal of Inorganic Chemistry, 1992, 8(1): 12-16 |
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| Authors: | Cao Xizhang Wang Xingqiao Zhang Milin Yang Guoyu |
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| Affiliation: | Department of Chemistry, Jilin University, Changchun 130023,Department of Chemistry, Jilin University, Changchun 130023,Department of Chemistry, Jilin University, Changchun 130023 and Department of Chemistry, Jilin University, Changchun 130023 |
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| Abstract: | Three new marked water-soluble metalloporphyrin complexes have been synthesized by a new method. They are 5,10,15,20-Tetrakis(P-N,N-dimethyl-N-sulfonic acid negative radical amino-benzene) porphyrin zinc, copper, cobalt ( Zn(II)TDMAPTPS, Cu(II)TDMAPTPS, Co(II)TDMAPTPS) and a new porphyrin, 5,10,15,20-Tetrakis(p-N,N-dimethyl-N-sulfonic acid negative radical) bi-N-propyl sulfonic acid porphyrin (TDMAPSPS). They have been characterized by infrared spectra, UV spectra, NMR and elementary analysis. Their structures have also been determined. Their light-sensitivity properties have been studied using the methods of fluorescence analysis and reductive reaction of methyl viologen and their intensities of light sensitivity are in the following order: Zn(II)TDMAPTPS>TDMAPSPS>Cu (II)TDMAPTPS > Co(II)TDMAPTPS. |
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| Keywords: | synthesis metalloporphyrin properties of light-sensitivity |
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