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Antimony—sulphur bonded compounds : IV. Further studies on the thermal decomposition of tetra-organoantimony mercaptides

Authors:	Bhupindher S Bedi Douglas W Grant Lesley Tewnion James L Wardell

Institution:	Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen AB9 2 UE Great Britain

Abstract:	The thermolytic decomposition of Ph₄SbSAr in organic solvents are reported. Solvent-derived products from decompositions in CCl₄ and cyclohexane confirm the free radical nature of the reactions.Thermal decompositions of Ph₃ (p-MeC₆H₄)SbSC₆H₄OMe-p, or Ph(p-MeC₆H₄)₃SbSC₆H₄X(Xp-MeO or H) provide mixed triarylstibines,Ph₃_nSb(C₆H₄Me-p)_n (n0, 1, 2 and 3), disulphide (XC₆H₄SSC₆H₄X), monosulphides (PhSC₆H₄X and p-MeC₆H₄SC₆H₄X), arenes, (PhH and PhMe) and biaryls (Ph₂,PhC₆H₄Me-p and p-MeC₆H₄C₆H₄Me-p).

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