]Preparation and x-ray crystal structure of biss(diphenylphosphino)methanido platinum(II), [Pt(Ph2PCHPPh2)2] |
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| Authors: | Michael P. Brwon Ahmad Yavari Ljubica Manojlovic-Muir Kenneth W. Muir Roger P. Moulding Kenneth R. Seddon |
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| Affiliation: | Donnan Laboratories, Liverpool University, P.O. Box 147, Liverpool L69 3BX Great Britain;Department of Chemistry, Glasgow University, Glasgow G12 8QQ Great Britain;Inorganic Chemistry Laboratory, Oxford University, Oxford OXI 3QR Great Britain |
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| Abstract: | [Pt(Ph2PCHPPh2)2], the first homoleptic complex containing the chelated bis(diphenylphosphino)methanide ligand, has been synthesised by reaction of K2[PtCl4] and Ph2PCH2PPh2 with KOH in ethanol, and characterised by 1H and 31P NMR spectroscopy and X-ray crystallography. |
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