On the mechanisms of silicon atom abstraction reactions |
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| Authors: | Elmer E Siepert Sheila D Witt Yl-Noo Tang |
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| Institution: | Department of Chemistry, Texas A&M University, College Station, Texas 77843 U.S.A. |
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| Abstract: | A set of experiment were designed to verify that recoil 31Si atoms abstracts H and F atoms via a stepwise mechanism instead of a simulatenous mechanism to give silylenes suh as 31SiH2, 31SiHF and 31SiF2. In addition, a novel compound 1-flourosilacyclopent-3-ene, was synthesized |
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