The reaction of formyl fluoride with transition metal complexes |
| |
| Authors: | Gerald Doyle |
| |
| Affiliation: | Exxon Research and Engineering Co., P.O. Box 45, Linden, NJ 07036 U.S.A |
| |
| Abstract: | Formyl fluoride reacts with metal carbonyl anions in a manner similar to acetic formic anhydride. Although formyl complexes may have been formed as unstable intermediates, no neutral formyl complexes could be isolated but rather the expected decomposition products, the metal carbonyl hydrides or ?imers, were produced. The attempted oxidative addition of formyl fluoride to various coordinately unsaturated metal complexes also did not result in the formation of formyl derivatives. HF adducts were obtained from the reaction ?fIr(CO)Cl(PR3)2 or M(PPh3)4 (M Pt or Pd) with formyl fluoride whereas Ru(NO)Cl(PPh3)2 and Rh(PPh3)3 Cl give the CO complexes Ru(NO)(CO)Cl(PPh3)2 and Rh(CO)Cl(PPh3)2, respectively. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
