Hydroformylation and hydrogenation of styrene with carbon monoxide and water catalyzed by iron carbonyls |
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| Authors: | József Palágyi László Markó |
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| Institution: | Institute of Organic Chemistry, University of Chemical Engineering, H-8200 Veszprém Hungary |
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| Abstract: | Styrene is hydrogenated to ethylbenzene and hydroformylated to 2- and 3- phenylpropanol by CO and H2O in the presence of a Fe3(CO)12 + Et3N + NaOH catalyst system at 140°C and 100 bar in H2O/MeOH. The product composition depends strongly on the H2O/MeOH ratio (A); alcohol formation is favoured at A 3/1 and ethylbenzene formation at A 1/2. 1,3-Diphenylbutane is formed as by-product. |
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