Haloalkyl complexes of the transition metals : II. Some new chloromethyl and methoxymethyl complexes of manganese,rhenium and ruthenium |
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| Authors: | John R Moss Simon Pelling |
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| Institution: | Department of Inorganic Chemistry, University of Cape Town, Rondebosch 7700 South Africa |
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| Abstract: | The reactions of NaMn(CO)5] or NaMn(CO)4(PPh3)] with CH2ClI yield the new chloromethyl complexes Mn(CO)5CH2Cl and Mn(CO)4(PPh3)CH2Cl. Reaction of NaRe(CO)5] or NaCpRu(CO)2] with ClCH2OMe yields Re(CO)5CH2Cl and CpRu(CO)2CH2Cl respectively, in addition to the corresponding methoxymethyl complexes (Cp = η5-C5H5). Reaction of CpRu(CO)2CH2OMe with HCl yields the corresponding chloromethyl complex. |
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