Asymmetric synthesis by chiral ruthenium complexes : VI. Enantiomer-discrimination in the hydrogen transfer from racemic alcohols to prochiral ketones in the presence of H4Ru4(CO)8[(−)-diop]2 |
| |
Authors: | Mario Bianchi Ugo Matteoli Piero Frediani Gloria Menchi Franco Piacenti |
| |
Affiliation: | Istituto di Chimica Organica dell''Università di Firenze, via Gino Capponi, 9, 50121 Firenze Italy |
| |
Abstract: | Hydrogen transfer from racemic alcohols to prochiral ketones in the presence of H4Ru4(CO)8[(?)-DIOP]2 has been examined. The enantiomer-discrimination is influenced by the structure of the reactants, temperature and the excess of phosphine present. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |