π-Olefin-iridium-komplexe : X. Einschiebung von diphenylacetylen in die methylen—iridium-bindung von bis(η4-cyclooctadien-μ-methylen-iridium) |
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Authors: | Jörn Müller Barbara Passon Joachim Pickardt |
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Institution: | Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, Strasse des 17. Juni 135, D-1000 Berlin 12 Deutschland |
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Abstract: | Bis(η4-cyclooctadiene-μ-methyleneiridium) reacts with acetylenes to yield various products. In the case of diphenylacetylene two compounds have been isolated from the reaction mixture and identified as a adduct containing a μ-η1, η3-1,2-diphenylallyl ligand (X-ray structure analysis), and as 1,2,4,5-tetraphenylbenzene. |
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