Darstellung,struktur und eigenschaften des dreikernigen titankomplexes (π-C2H5)2TiClOTi(π-C5H5)ClOTiCl(π-C5H5)2·CHCl3 |
| |
Authors: | Heinz-Peter Klein Ulf Thewalt Karl Döppert Roberto Sanchez-Delgado |
| |
Institution: | Sektion für Röntgen- und Elektronenbeugung, Universität Ulm, Oberer Eselsberg, D-7900 Ulm B.R.D.;Instituto Venezolano de Investigaciones Cientificas (IVIC), Centro de Quimica, Aptdo. 1827, Caracas 1010A Venezuela |
| |
Abstract: | The trinuclear titanium(IV) complex (π-C5H5)2TiClOTi(π-C5H5)ClOTiCl(π-C5H5)2 · CHCl3 is formed by hydrolysis of (π-C5H5)2TiCl2 at pH > 3.5 and can be isolated in the crystalline state from the reaction of (π-C5H5)2TiCl2 with Ag2O and water in chloroform. Its structure is determined by X-ray analysis. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |