Reaction of coordinated phosphines: VI. Divalent palladium promoted cleavage of carbon—phosphorus bonds in tertiary phosphines |
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| Authors: | Kiyoshi Kikukawa Tsutomu Matsuda |
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| Institution: | Department of Organic Synthesis, Faculty of Engineering, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812 Japan |
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| Abstract: | The important role of divalent palladium in the cleavage of carbon—phosphorus bond of tertiary phosphines is revealed by the study of the phenylation in the Pd(OAc)2Ph3P-styrene system under various conditions; reaction atmosphere, ratio of Ph3P/Pd(OAc)2, and addition of ethanol or CuII(OAc)2 · H2O. |
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