Photoinduced synthesis of the mixed metal “manganese rhenium cubane” [Mn3Re(CO)12(SC6H5)4] |
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| Authors: | P Jaitner |
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| Institution: | Institut für Anorganische und Analytische Chemie der Universität Innsbruck, Innrain 52a, A-6020 Innsbruck Austria |
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| Abstract: | The photoinduced synthesis and spectroscopic properties of the new mixed metal compound Mn3Re(CO)12(SC6H5)4] by UV irradiation of a mixture of Mn2(CO)10, Re2(CO)10 with S2(C6H5)2 is described. No mixed sulphur/selenium compounds M4(CO)12SnSe4?n(C6H5)4] (M = Mn or Re, n = 1–3) could be obtained by analogous photoreactions. |
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