The hydrogenation of styrenes by hydridocobalt tetracarbonyl |
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| Authors: | Jerome A Roth Paul Wiseman Lois Ruszala |
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| Institution: | Chemistry Department, Northern Michigan University, Marquette, Michigan 49855 U.S.A. |
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| Abstract: | The rates of hydrogenation of several styrene derivatives by stoichiometric hydridocobalt tetracarbonyl HCo(CO)4] were measured and compared. The relative rates are discussed in terms of conjugative and steric effects on the geminate radical pair mechanism. An improved method for determining HCo(CO)4 concentration is described. |
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