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Syntheses a l'aide de sulfones : XXIII. Sur la selectivite de la synthese des sulfones Allyliques
Authors:Marc Julia  Maurice Nel  Anne Righini  Daniel Uguen
Affiliation:E.N.S., Laboratoire de Chimie, 24, rue Lhomond, 75231 Paris Cédex 05 France
Abstract:The role of the palladium ligands on the yield and regioselectivity of the reaction of conjugated dienes with arenesulphinic acids (or of allylic acetates with sodium arenesulphinates) has been investigated. Arenesulphinic acids catalyse the isomerisation of allylic sulphones.
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