Synthesis of lipooligosaccharides related to nodulation factors ofRhizobium sp. NGR234 |
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Authors: | A I Zinin V I Torgov V N Shibaev A S Shashkov W J Broughton |
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Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation;(2) Laboratory of Molecular Biology of Higher Plants, University of Geneva, 1 ch. de l'Impératrice, 1292 Chambesy-Genève, Switzerland |
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Abstract: | Trisaccharide analogs of natural nodulation factors fromRhizobium sp. NGR234, namely, 2-acetamido-2-deoxy-4-O-(2-deoxy-2-hexadecanamido-β-d-glucopyranosyl)-6-O-(2-O-methyl-α-l-fucopyranosyl)-d-glucopyranose and its derivatives containing a 4-O-acetyl or a 3-O-sulfo group at thel-fucose residue, were synthesized. The oligosaccharides synthesized were shown to posses biological activity.
Laboratoire de Biologie Moléculaire des Plantes Supérieures (LBMPS), Université de Genève, 1 ch. de l'Impératrice, 1292 Chambesy-Genève,
Suisse.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya No. 3, pp. 513–518, March, 1998. |
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Keywords: | Nod-factors trisaccharides lipooligosaccharides Rhizobia |
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