A chiral porous 3D metal-organic framework with an unprecedented 4-connected network topology |
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| Authors: | Wu Chuan-De Lin Wenbin |
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| Institution: | Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599, USA. |
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| Abstract: | A novel homochiral 3D metal-organic framework CdL2(H2O)2]ClO4]2.2DMF.3EtOH.5/3H2O, 1, (L =(R)-6,6-dichloro-2,2-diethoxy-1,1-binaphthyl-4,4-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies. |
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