Experimental and theoretical results on palladium-catalyzed hydrogenation reactions |
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Authors: | R. Gomez and O. Novaro |
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Affiliation: | (1) Dept. de Química, Universidad Autónoma Metropolitana, A.P. 55-534, 09340 Mexico, D.F.;(2) Gewrencia de Investigación Básica de Procesos, Instituto Mexicano de Pertróleo, A.P. 14-805, 07730 México., D.F. |
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Abstract: | A correlation between the stereoselectivity of cis-and trans-1, 2-dimethylcyclohexane in o-xylene hydrogenation and theoretical charge density of Pd centers as a function of particle size has been established.
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On sabbatical leave from Instituto de Fisica UNAM. |
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