Synthesis of indole alkaloid (−)-corynantheidol and formal synthesis of (−)-corynantheidine via one-pot asymmetric azaelectrocyclization |
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| Authors: | Yanwu Li |
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| Institution: | Department of Chemistry and Open Research Center on Organic Tool Molecules, School of Science and Technology, Kwansei Gakuin University, Sanda, Hyogo 669-1337, Japan |
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| Abstract: | The highly efficient asymmetric total synthesis of indole alkaloid, (−)-corynantheidol, containing a 2,4,5-trisubstituted piperidine core, was achieved using a new version of the one-pot azaelectrocyclization reaction. The formal synthesis of (−)-corynantheidine was also achieved using the common synthetic intermediate for these corynantheines. |
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| Keywords: | &minus" target="_blank">(&minus )-Corynantheidol Synthesis One-pot Azaelectrocyclization Piperidine |
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