Transformations of imidazo[4, 5-f]quinoline |
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Authors: | A M Simonov B I Khristich V G Poludnenko |
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Institution: | (1) Rostov-on-Don State University, USSR |
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Abstract: | Treatment of imidazo4, 5-f]quinoline and some of its 3-substitmion products with methyl halides and methyl benzenesulfonate gives as the main reaction products N-methylimidazoquinolinium salts, which can also be synthesized from 5, 6-dimainoquinolines. Methylation at the N atom of the imidazole ring is only a side reaction. Treatment with trimethylphenylammonium hydroxide introduces a methyl radical into the NH group of imidazoquinoline, giving a mixture of 1-and 3-substitution products. |
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