Analysis of reaction by-products in ethylene oligomers by capillary gas chromatography |
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| Authors: | A Orav K Kuningas E Koplimets S Rang |
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| Institution: | (1) Institute of Chemistry, Estonian Academy of Sciences, Akadeemia tee 15, EE-0026 Tallinn, Estonia |
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| Abstract: | Summary A gas chromatographic method using temperature-programmed poly-dimethylsiloxane OV-101 and poly(pheny ether) (5 rings) capillary columns was developed to separate and quantify the reaction by-products in ethylene oligomers. It was found that the content of 2-alkyl-1-alkenes, 2-alkenes and n-alkanes in the C8–C18  -olefin fractions amounts to 29, 10 and 2.6% respectively. |
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| Keywords: | Gas chromatography Quantitative analysis Ethylene oligomer by-products n-Alkanes n-alkenes and 2-alkyl-1-alkenes |
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