| 二-对异丙基亚砜的合成及用纸色谱法研究其萃取和分离性能 |
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| 引用本文： | 许晓文,李玲颖,高冬君,肖振平. 二-对异丙基亚砜的合成及用纸色谱法研究其萃取和分离性能[J]. 高等学校化学学报, 1988, 9(3): 230 |
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| 作者姓名： | 许晓文 李玲颖 高冬君 肖振平 |
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| 作者单位： | 南开大学化学系 |
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| 摘 要： | 用Friedel-Crafts反应合成了二-对异丙笨亚砜,确定了它的组成和结构,测试了近紫外吸收光谱、薄层色谱行为。用反相纸色谱法在HCl和HNO3中观察了它对40余种离子的革取能力,并在纸上分离了Au-Pd、Au-Ag、Au-Pt、Au-Tl、Os-Ru、Os-Ir、Zr-Hf、Mo-W等离子对。
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| 收稿时间： | 1986-09-30 |
Synthesis of Di-p-Isopropylphenyl Sulf oxide and Study on It's Separation and Extraction Behavior by Paper Chromatography |
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| Xu Xiaowen,Li Lingying,Gao Dongjun,Xiao Zhenpin. Synthesis of Di-p-Isopropylphenyl Sulf oxide and Study on It's Separation and Extraction Behavior by Paper Chromatography[J]. Chemical Research In Chinese Universities, 1988, 9(3): 230 |
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| Authors: | Xu Xiaowen Li Lingying Gao Dongjun Xiao Zhenpin |
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| Affiliation: | Department of Chemistry, Nankai University, Tianjin |
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| Abstract: | In this paper di-p-isopropylphenyl sulfoxide (PlPSO) was first synthesized by Friedel-Crafts reaction.The elemental composition and the structural characteristics of this suifoxide were determined by elemental analysis, 1H NMR, 13CNMR, and IR.It's UVspectrum and TLCbehavior were also investigated.It's extraction behavior to more than 40 metallic ions in both HCl and.HNO3 systems were observed by reversed paper chromatography.It could be used as a stationary phase in the reversed paper chromatography successfully to separate some metal ion couples, such as Au-Pd, Au-Ag, Au-Pt, Au-Tl, Os-Ru, Os-Ir, Zr-Hf, Mo-W and others. |
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