Calorimetric study of solvation of alkanes with mixtures of acetone or 1,4-dioxane with 1-octanol at 25°C |
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Authors: | V P Korolev N L Smirnova N A Litova |
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Institution: | (1) Institute of Chemistry of Solutions, Russian Academy of Sciences, Ivanovo, Russia;(2) Ivanovo State University of Chemical Engineering, Ivanovo, Russia |
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Abstract: | Heats of solution of cyclohexane and squalane in mixtures of 1-octanol with acetone or 1,4-dioxane within the entire range of compositions were measured calorimetrically. The enthalpies of solution of cyclohexane, squalane, and hexadecane in the mixtures of acetone or 1,4-dioxane with 1-octanol show linear correlation. Enthalpies of solvation of propane, decane, and eicosane in these mixtures were calculated. |
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