Reaction of <Emphasis Type="Italic">N</Emphasis>-methyl-<Emphasis Type="Italic">N,N</Emphasis>-bis(silatranylmethyl)amine with trichlorosilane |
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| Authors: | N F Lazareva I M Lazarev |
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| Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia |
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| Abstract: | N,N-Bis(silatranylmethyl)methylamine reacts with trichlorosilane to form the amine hydrochloride and perchloropolysilane, the
product of polymerization of dichlorosilylene. In the presence of 1,3-butadiene the main products of the reaction are the
amine hydrochloride and 1,1-dichlorosilacyclopentene-3, the product of 1,4-addition of dichlorosilylene to 1,3-butadiene. |
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