Structure of intercalated Cs in zeolite ITQ-4: an array of metal ions and correlated electrons confined in a pseudo-1D nanoporous host |
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| Authors: | Petkov V Billinge S J L Vogt T Ichimura A S Dye J L |
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| Affiliation: | Department of Physics and Astronomy and Center for Fundamental Materials Research, Michigan State University, East Lansing 48824, USA. |
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| Abstract: | The presence of Cs+ ions in the pseudo-1D nanopores of zeolite ITQ-4, Si32O64, is confirmed by x-ray diffraction and atomic pair distribution function analysis. Inside the nanopores the Cs+ ions are found to assemble in zigzag chains and thus form an extended, positively charged sublattice providing charge balance for a low-density electron gas also confined to the nanopores. |
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