Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct |
| |
| Authors: | Grasa Gabriela A Singh Rohit Scott Natalie M Stevens Edwin D Nolan Steven P |
| |
| Institution: | Department of Chemistry, University of New Orleans, New Orleans, LA-70148, USA. |
| |
| Abstract: | The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
