Highly Selective and Stable Florescent Sensor for Cd(II) Based on Poly(azomethine-urethane) |
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Authors: | İsmet Kaya Musa Kamacı |
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Institution: | 1. Department of Chemistry, Faculty of Sciences and Arts, ?anakkale Onsekiz Mart University, 17020, ?anakkale, Turkey 2. Department of Chemistry, Kamil ?zda? Science Faculty, Karamano?lu Mehmetbey University, 70100, Karaman, Turkey
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Abstract: | In this study a kind of poly(azomethine-urethane); (E)-4-((2 hydroxyphenylimino) methyl)-2-methoxyphenyl 6-acetamidohexylcarbamate (HDI-co-3-DHB-2-AP) was prepared as in the literature and employed as a new fluorescent probe for detection of Cd(II) concentration. The photoluminescence (PL) measurements were carried out in the presence of several kinds of heavy metals. HDI-co-3-DHB-2-AP gave a linearly and highly stable response against Cd(II) as decreasing a new emission peak at 562 nm. Possible interferences of other ions were found too low. Detection limit of the sensor was found as 8.86?×?10?4?mol?L?1. Resultantly, HDI-co-3- DHB-2-AP could be effectively used as an optical Cd(II) sensor. |
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