Reaction of 3-carene with perfluoroalkanoic acids |
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Authors: | Yu G Trishin A N Fedorov |
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Institution: | 1.Higher School of Technology and Energetics,St. Petersburg State University of Industrial Technologies and Design,St. Peterburg,Russia |
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Abstract: | The addition of perfluoroalkanoic acids to 3-carene involves opening of the cyclopropane ring at the peripheral bonds with formation of a mixture of isomeric p-menth-1-en-8-yl and m-menth-1-en-8-yl perfluoroalkanoates. The reaction rate decreases as the length of the perfluoroalkyl radical of the acid increases. Trichloroacetic acid reacted with 3-carene at a lower rate than does trifluoroacetic acid, but the products are analogous p-menth-1-en-8-yl and m-menth-1-en-8-yl trichloroacetates. |
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