Synthesis and oxidation of sulfides based on caryophyllene oxide and phenylmethanethiol |
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Authors: | Yu V Gyrdymova E S Izmest’ev S A Rubtsova A V Kutchin |
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Abstract: | Lewis acid-catalyzed reaction of (–)-caryophyllene oxide with phenylmethanethiol gave sulfides with clovane and caryophyllane structure which were oxidized to the corresponding sulfoxides and sulfones in 74 and 84% yield, respectively. |
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