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Interactions of Proline in Non-aqueous Anionic, Cationic and Nonionic Surfactants at Different Temperatures
Authors:Anwar Ali  Shahjahan
Affiliation:Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi-110 025, India
Abstract:Density and viscosity data of proline (Pro) in sodium dodecyl sulfate/cetyltrimethylammonium bromide/poly (oxyethylene) isooctyl phenyl ether in formamide were measured at 298.15, 303.15, 308.15, and 313.15 K and 0.1 MPa. The density data were utilized to evaluate standard partial molar volumes (View the MathML source) and partial molar isobaric expansibility (View the MathML source). The viscosity data were used to evaluate A- and B-coefficients, free energy of activation of viscous flow (View the MathML source) and (View the MathML source), per mole of solvent and solute respectively, enthalpy (ΔH*) and entropy (ΔS*) of activation of viscous flow. The results obtained were utilized in the qualitative elucidation of the Pro-surfactant/formamide and Pro-Pro interactions in the present systems.
Keywords:Partial molar volume   Viscosity coefficient   Interaction
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