Interactions of Proline in Non-aqueous Anionic, Cationic and Nonionic Surfactants at Different Temperatures |
| |
Authors: | Anwar Ali Shahjahan |
| |
Affiliation: | Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi-110 025, India |
| |
Abstract: | Density and viscosity data of proline (Pro) in sodium dodecyl sulfate/cetyltrimethylammonium bromide/poly (oxyethylene) isooctyl phenyl ether in formamide were measured at 298.15, 303.15, 308.15, and 313.15 K and 0.1 MPa. The density data were utilized to evaluate standard partial molar volumes () and partial molar isobaric expansibility (). The viscosity data were used to evaluate A- and B-coefficients, free energy of activation of viscous flow () and (), per mole of solvent and solute respectively, enthalpy (ΔH*) and entropy (ΔS*) of activation of viscous flow. The results obtained were utilized in the qualitative elucidation of the Pro-surfactant/formamide and Pro-Pro interactions in the present systems. |
| |
Keywords: | Partial molar volume Viscosity coefficient Interaction |
本文献已被 ScienceDirect 等数据库收录! |
|