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| 苯并[de]蒽-7-酮类叔芳胺的合成及其发光性能的研究 | |
| 引用本文： | 余明新,康君辉,郑建鸿. 苯并[de]蒽-7-酮类叔芳胺的合成及其发光性能的研究[J]. 有机化学, 2008, 28(8): 1393-1397 |
| 作者姓名： | 余明新 康君辉 郑建鸿 |
| 作者单位： | 1. 浙江大学化学系,杭州,310027;台湾清华大学化学系,新竹,30043 2. 浙江大学化学系,杭州,310027 3. 台湾清华大学化学系,新竹,30043 |
| 基金项目： | 浙江省工业催化重中之重学科开放基金，浙江省教育厅资助项目 |
| 摘 要： | 芳基伯胺与芳基溴在Pd(dba)2/P(t-Bu)3催化下于80 ℃甲苯溶液中反应生成芳基仲胺, 芳基仲胺再与3-溴苯并[de]蒽-7-酮在Pd(OAc)2/P(t-Bu)3催化下于120 ℃邻二甲苯溶液中反应生成苯并[de]蒽-7-酮类叔芳胺有机电致发光材料; 3-二苯基氨基苯并[de]蒽-7-酮与丙二腈反应生成2-(3-二苯基氨基)苯并[de]蒽-7-基亚基丙二腈. 产物的结构经1H NMR, 13C NMR, 13C (DEPT), HRMS光谱所证实. 用UV-Vis, PL, DSC测定了化合物的发光性能. |
| 关 键 词： | 苯并[de]蒽-7-酮 2-(3-二苯基氨基)苯并[de]蒽-7-基亚基丙二腈 叔芳胺 钯催化 发光性能 |
| 收稿时间： | 2007-10-13 |
| 修稿时间： | 2008-01-03 |
Synthesis of Diarylamino-benzo[de]anthracen-7-ones and Their Light Emitting Property |
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| YU,Ming-Xin,KANG,Jun-Hui,CHENG,Chien-Hong. Synthesis of Diarylamino-benzo[de]anthracen-7-ones and Their Light Emitting Property[J]. Chinese Journal of Organic Chemistry, 2008, 28(8): 1393-1397 | |
| Authors: | YU Ming-Xin KANG Jun-Hui CHENG Chien-Hong |
| Affiliation: | (a Department of Chemistry, Zhejiang University, Hangzhou 310027) (b Department of Chemistry, Tsinghua University, Hsinchu 30043) |
| Abstract: | The primary arylamines reacted with aryl halides to give the secondary arylamines by the catalysis of Pd(dba)2/P(t-Bu)3 at 80 ℃ in toluene. The secondary arylamines reacted with 3-bromo-benzo[de]- anthrax-cen-7-one to afford the organic light-emitting device (OLED) material of diarylamino- benzo[de]anthracen-7-ones type by the catalysis of Pd(OAc)2/P(t-Bu)3 at 120 ℃ in o-xylene. Reaction of 3-diphenylamino-benzo[de]anthracen-7-one with malononitrile gives 2-(3-diphenylamino-benzo[de]- anthracen-7-ylidene)-malononitrile. The product structures were demonstrated by 1H NMR, 13C NMR, 13C (DEPT), HRMS spectra. Light emitting properties were examined by UV-vis, PL and DSC spectra. |
| Keywords: | benzo[de]anthracen-7-one 2-(3-diphenylamino-benzo[de]anthracen-7-ylidene)-malononitrile tertiary arylamine palladium catalyst light emitting property |
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