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Triple ion formation in solutions of alkaline sulfocyanides |
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| Authors: | P Bacelon J Corset C de Loze |
| Institution: | (1) Laboratoire de Spectrochimie Infrarouge et Raman, CNRS, 2, Rue Henri Dunant, 94320 Thiais, France |
| Abstract: | Through the infrared and Raman spectra of alkaline sulfocyanides in high-and low-polarity media, nitromethane (CH3NO2) and tetrahydrofuran (THF), triple cations and triple anions may be characterized. The formation of these species at the expense of ion pairs or more aggregated species such as dimers is discussed taking into account cation solvation, anion solvation, and the influence of cation-anion interaction. |
| Keywords: | Infrared-Raman study ionic association-solution triple ions aprotic solvents nitromethane tetrahydrofuran alkaline and tetraalkylammonium sulfocyanides |
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