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茜素S复合铋膜电极电催化还原氯霉素
引用本文:李志英,肖阳,周长利,孙旦子. 茜素S复合铋膜电极电催化还原氯霉素[J]. 分析试验室, 2011, 30(3): 35-39
作者姓名:李志英  肖阳  周长利  孙旦子
作者单位:济南大学化学化工学院,济南,250022
基金项目:济南大学校博士基金项目,山东省自然科学基金项目
摘    要:本研究采用电化学法制备茜素S复合铋膜修饰玻碳电极,利用循环伏安法、差示脉冲伏安法(DPV)研究氯霉素在茜素S复合铋膜电极上的电化学行为,并对其电化学测试条件进行优化.在pH 7.0的KH2PO4-Na2HPO4缓冲溶液中,氯霉素在-0.63 V处产生一灵敏的不可逆还原峰,显示出复合铋膜对氯霉素的还原有很好的催化作用.D...

关 键 词:茜素S复合铋膜电极  氯霉素  差示脉冲伏安法

Electrocatalytic reduction of chloramphenicol on a bismuth/alizarin S film electrode
LI Zhi-ying,XIAO Yang,ZHOU Chang-li,SUN Dan-zi. Electrocatalytic reduction of chloramphenicol on a bismuth/alizarin S film electrode[J]. Chinese Journal of Analysis Laboratory, 2011, 30(3): 35-39
Authors:LI Zhi-ying  XIAO Yang  ZHOU Chang-li  SUN Dan-zi
Affiliation:LI Zhi-ying,XIAO Yang,ZHOU Chang-li and SUN Dan-zi(School of Chemistry and Chemical Engineering,University of Jinan,Jinan 250022)
Abstract:This article covers the preparation of a bismuth/alizarin S composite film-coated glassy carbon electrode and the eletrochemical determination of chloramphenicol by cyclic voltammetry and differential pulse voltammetry with the composite bismuth electrode.The new electrode shows an obvious electrocatalytic activity for the reduction of chloramphenicol and presents well-defined,reproducible and sharp signal.Factors influencing the determination performance including the film preparation,scan rate and solutio...
Keywords:Bismuth/alizarin S film electrode  Chloramphenicol  Differential pulse voltammetry  
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