Decomposition of hexafluoropropylene oxide in a strong IR field |
| |
Authors: | V. A. Dunyakhin O. V. Kuricheva V. V. Timofeev Yu. N. Zhitnev |
| |
Affiliation: | (1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
| |
Abstract: | Multiphoton dissociation (MPD) of hexafluoropropylene oxide (HFPO) under focused CO2-laser radiation was studied. A high-energy channel of HFPO decomposition was revealed. The dependences of the MPD yield and the ratio between various channels of HFPO decomposition on the laser radiation frequency in the range from 967.7 to 1090.0 cm–1, the incident radiation energy, and the initial pressure of HFPO were obtained. A considerable contribution of thermal decomposition of HFPO occurring outside of the irradiated zone to the total yield of its decomposition was established. An explanation for the pressure dependence of the yield of HFPO decomposition was suggested.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2174–2180, November, 1995.The authors are grateful to the Russian Foundation for Basic Research for financial support of this work (Project No. 94-03-09059). |
| |
Keywords: | multiphoton dissociation hexafluoropropylene oxide carbenes thermal decomposition MPD spectrum |
本文献已被 SpringerLink 等数据库收录! |
|